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Conductive Wool Yarns by Continuous Vapor Phase Polymeriation of Pyrrole

Written By Wednesday, October 26, 2022 Add Comment Edit

Abstract

Yarn-shaped supercapacitors are favored due to their small size, high specific capacitance, and light weight. Herein, we reported a distinctive type of ply twist yarn supercapacitor by in situ polymerization of pyrrole on carbon nanotubes (CNTs)/cotton ring spun yarns. CNTs and polypyrrole (PPy) were successfully embedded into the cotton yarns with a ply twist structure. The as-developed electrode exhibited excellent electrical conductivity (20 Ω/cm), good mechanical properties (59.8 MPa, 24.6%), a high specific capacitance of 386.5 mF/cm2 with the current density of 1 mA/cm2, and ideal cycle stability with the retention of 87.8% after 5000 cycles. Meanwhile, the assembled supercapacitor showed a power density of 278.4 μW/cm2 and an energy density of 13.21 μWh/cm2. It also presented outstanding capacitive performance under different angles. This facile ply twist method provided new possibilities for one-dimensional (1D) supercapacitor and flexible wearable electronics applications.

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Funding

This work was supported by the Natural Science Foundation of Hubei Province (Grant No. 2019CFB290), the Scientific Research Project of Hubei Provincial Department of Education (Grant No. Q20191701), and Hubei Province Technical Innovation Special Project (2019AAA005).

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Authors and Affiliations

  1. State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan, 430200, China

    Baowei Hao, Zhongmin Deng, Shuguang Bi, Jianhua Ran, Deshan Cheng, Lei Luo, Guangming Cai & Xiaoning Tang

  2. Centre for Materials Innovation and Future Fashion, School of Fashion and Textiles, RMIT University, Brunswick, 3056, Australia

    Xin Wang

Corresponding authors

Correspondence to Lei Luo, Guangming Cai or Xin Wang.

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Hao, B., Deng, Z., Bi, S. et al. In situ polymerization of pyrrole on CNT/cotton multifunctional composite yarn for supercapacitors. Ionics 27, 279–288 (2021). https://doi.org/10.1007/s11581-020-03784-2

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  • DOI : https://doi.org/10.1007/s11581-020-03784-2

Keywords

  • CNT/cotton yarn
  • Supercapacitor
  • Nanocomposites
  • Conductivity
  • Electrochemical

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